Abstract:
This research work describes the determination of the levels of nitrogen monoxide, nitrogen dioxide (termed as NOX) and sulphur dioxide (SO2) in Nairobi city by use of passive sampling method. In this technique, Triethanolamine (TEA) and potassium tetrachloromercurate (TCM) solutions were used as trapping agents and air samples which were sampled from twelve sites within Nairobi city were analyzed spectrophotometrically. The detection limit of passive sampling method was found to be 7μg/m3 and 4 μg/m3 and precision was 4 μg/m3 and 3 μg/m3 for NO2 and SO2, respectively for a 24-hour sampling. The highest 24-hour mean concentrations of NOX and SO2 were recorded at City Kabanas site along Nairobi-Mombasa road with 300.61 8.21 μg/m3 and 181.35 2.46 μg/m3, respectively and the lowest mean concentrations of NOX and SO2 were recorded at Githurai site with 169.92 6.12 μg/m3and 85.60 0.78 μg/m3, respectively. The overall mean levels for these air pollutants were; 82.87 ± 6.13 μg/m3 for NO, 136.78 ± 9.72 μg/m3 for NO2 and 127.66 ± 10.45 μg/m3 for SO2. The recorded level of NO2 in Nairobi troposphere was found to be above the WHO value of 100μg/m3, that of SO2 was within the WHO value of 125μg/m3 and that of NO was below the WHO value of 400μg/m3. Furthermore, it was found that levels of NOX and SO2 recorded during the dry season were higher than those of the wet season. The trend of levels of NOX and SO2 followed the vehicular density and areas with high vehicular traffic and industrial activities had high levels of NOX and SO2.
